2-Phenyl-2-propyl benzodithioate 99% (HPLC) | Sigma …
The preparation of liquid-filled (isooctane core) polystyrene nanocapsules by RAFT miniemulsion polymerization has been reported. Although good control over polymerization was obtained with both cumyl dithiobenzoate 9 and dithiophenylacetate 38, significant retardation was observed with the dithiobenzoate RAFT agent and it was proposed this prevented development of the desired core–shell morphology.
2-Phenyl-2-propyl benzodithioate ..
AB - A facile method to prepare cationic cobaltocenium-containing polyelectrolyte is reported. Cobaltocenium monomer with methacrylate is synthesized by copper-catalyzed azide-alkyne cycloaddition (CuAAC) reaction between 2-azidoethyl methacrylate and ethynylcobaltocenium hexafluorophosphate. Further controlled polymerization is achieved by reversible addition- fragmentation chain transfer polymerization (RAFT) by using cumyl dithiobenzoate (CDB) as a chain transfer agent. Kinetic study demonstrates the controlled/living process of polymerization. The obtained side-chain cobaltocenium-containing polymer is a metal-containing polyelectrolyte that shows characteristic redox behavior of cobaltocenium. A facile synthesis method to functional cobaltocenium-containing polyelectrolyte is reported. By using click chemistry and RAFT, the functional cationic cobaltocenium polymer is prepared from un-substituted cobaltocenium. The obtained polymer shows characteristic UV-vis absorption peaks and redox properties of the cobaltocenium group.
A PHEMA brush was formed on a poly(tetrafluoroethylene--hexafluoropropylene) (FEP) film by first carrying out surface modification with an oxygen plasma to introduce peroxide functionality. This functionality was used to initiate RAFT polymerization of HEMA in the presence of cumyl dithiobenzoate to produce FEP--(PHEMA).
Cumyl Dithiobenzoate | Sigma-Aldrich
A detailed study of the product of RAFT polymerization of MA with both cumyl dithiobenzoate and cumyl dithiophenylacetate using coupled size exclusion chromatography–electrospray ionization mass spectrometry has been carried out with a view to detecting products which might be formed by a side reaction of the intermediate radical by radical–radical termination. As in previous studies of this nature, these were not detected.
Search results for Cumyl Dithiobenzoate at Sigma-Aldrich
Porous silica particles surface were modified by immobilization of 2,2-azobis(2-cyanopentanoic acid) and grafted with MAA-EGDMA by RAFT polymerization with cumyl dithiobenzoate in the presence of -phenylalanine anilide to leave a crosslinked molecularly imprinted film which was used as a chromatographic support.
Silica‐immobilized cumyl dithiobenzoate as mediating …
PBA and PDMA grafts have been formed on poly(divinylbenzene) microspheres. The process involved RAFT polymerization of the monomer in the presence of microspheres prepared by precipitation polymerization and which possess pendant double bonds. Cumyl dithiobenzoate 9 was used as RAFT agent.